Positive deviation from ideal behaviour is due to the fact that

  • A
    Molecular attractions play dominant role
  • B
    Molecular volume plays dominant role
  • C
    Vander Waal constant $a$ dominates over $b$
  • D
    Molecular attractions cancel the effect of molecular volume

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Similar Questions

The graph between $P$ and $V$ below the critical temperature is:

Pressure versus volume graph for a real gas and an ideal gas are shown in the figure. Answer the following questions on the basis of this graph:
$(i)$ Interpret the behaviour of real gas with respect to ideal gas at low pressure.
$(ii)$ Interpret the behaviour of real gas with respect to ideal gas at high pressure.
$(iii)$ Mark the pressure and volume by drawing a line at the point where real gas behaves as an ideal gas.

For a real gas,the ratio $\frac{T_{C} \text{ (Critical temperature)}}{P_{C} \text{ (Critical pressure)}}$ is equal to:

Which among the following statements is/are incorrect regarding real gases?
$(i)$ Their compressibility factor is never equal to unity $(Z \neq 1)$.
$(ii)$ The deviations from ideal behavior are less at low pressures and high temperatures.
$(iii)$ Intermolecular forces among gas molecules are equal to zero.
$(iv)$ They obey Van der Waals equation,$PV = nRT$.

$A$ certain quantity of real gas occupies a volume of $0.15 \ dm^3$ at $100 \ atm$ and $500 \ K$ when its compressibility factor is $1.07$. Its volume at $300 \ atm$ and $300 \ K$ (when its compressibility factor is $1.4$) is $........ \times 10^{-4} \ dm^3$ (Nearest integer).

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